The famous nocturnal Hex hatch of the Midwest (and a few other lucky locations) stirs to the surface mythically large brown trout that only touch streamers for the rest of the year.
Trout are selective to color and shape in inverse ratio to the intensity of light. In other words trout are more selective in the early morning and in the evening and on dark days than they are when the sun is shining brightly on the water. For this reason, if the trout will feed at all during the middle of the day, then a bright day will be the best sort of day on which to fool them.
As a general conscenous morning and evening fishing is "easier" due to low light conditions. I believe this has become an axiom because said lighting conditions hide mistakes made by the angler in approach and presentation and has little to do with how well the fish actually see the fly.